Back in 2010, divers off the coast of Finland stumbled upon some astonishingly old booze: champagne and beer preserved underwater in a 170-year-old shipwreck. Naturally, they had a taste. But now scientists are back with a rigorous chemical analysis of the beers.
In the initial taste tests, the beer was so sour no one would tell how they were originally meant to taste. But when our noses falter, we have machines. Chemists at VTT Technical Research Centre of Finland looked at two particular bottles of recovered beer, which they called A56 and C49. Before they ran any tests, they recorded their own impressions of the beer's smells, which seem, erh, largely unpleasant.
Bubbles of gas, presumably CO2, formed during sampling, producing a light foam. Both beers were bright golden yellow, with little haze. Both beers smelt of autolyzed yeast, dimethyl sulfide, Bakelite, burnt rubber, over-ripe cheese, and goat, with phenolic and sulfury notes.
Both bottles contained much more salt than usual, suggesting the beers had been diluted with seawater. With modern chemistry techniques, scientists are able to separate out individual compounds and by accelerating them through an electric field, figure out their molecular composition, which cuts through the sourness and saltiness to the beer's true character, in other words.
A56 and C49 turned out to clearly be different beers. C49 was much hoppier and thus more bitter. An analysis of yeast-derived flavour compounds also revealed rose and sweet apples flavours that were high in A56. C49 had a higher concentration of flavour compounds for green tea.
Some flavour differences may be because of how beer was brewed differently in the 19th century. For example, A56 contained much more of a compound called furfural, which is possibly the result of mash being heated over an open fire. Both beers, even when they were fresh, were also more sour than your average modern brew. It wasn't until the late 19th century that brewers learned how to keep acid-producing bacteria out of beer. Until that breakthrough, pretty much all beer, including A56 and C49, was sour beer.
Back when the shipwreck was first discovered, chemists began analysing the beer with an eye toward recreating it. But the study published in the Journal of Agricultural and Food Chemistry makes no mention of live yeast cells found in the beers, which makes the whole endeavour a lot more difficult. On the other hand, this study is the first step in a forensic beer reconstruction. [Journal of Agricultural and Food Chemistry]
Top image: American Chemical Society